Thursday, August 20, 2015

White Foam in Tianjin is hydrogen Cyanide

When rain hits Sodium cyanide it creates hydrogen cyanide which is a flammable gas which interferes with breathing and sometimes explodes under the right conditions.
 I was also reading that a human will die within 30 to 60 minutes when exposed to enough of it.

note: I cannot say that the white foam is (Only Hydrogen Cyanide) because there are a total of 40 extremely hazardous chemicals that were blown all over the place in now multiple exlosions (the two really big ones that took out all the windows of high rise apartments and put about 700 people in the hospital with shards of glass harming them when the windows blew out at about 11 pm that night. and many many small explosions likely partly caused by Hydrogen Cyanide blowing up because of the rain interaction with Sodium Cyanide. Also, Potassium nitrate likely was what blew the whole thing up in the first place because of so much being stored there.

So, the white foam likely is primarily Hydrogen Cyanide with 39 other very poisonous elements likely involved too. What they all have now made together when added to the environment there is anyone's guess. If there were statistics you likely could tell within a year because of the types of deaths and ailments of people who choose to continue to live there.  My thought is that leaving if economically possible from this area would be a very good idea as soon as possible for anyone who can. end note.

  1. Hydrogen cyanide - Wikipedia, the free...

    en.wikipedia.org/wiki/Hydrogen_cyanideCached
    Hydrogen cyanide (HCN), sometimes called prussic acid, is an organic compound with the chemical formula HCN. It is a colorless, extremely poisonous liquid that boils ...
  2. Hydrogen Cyanide Emergency Response Card (NIOSH)

    www.cdc.gov/niosh/ershdb/EmergencyResponseCard_29750038.htmlCached
    May 31, 2015 · Indoor Air: Hydrogen cyanide (AC) can be released into indoor air as a liquid spray (aerosol) or as a gas. Water: Hydrogen cyanide (AC) can be used to ...
  3. Mar 04, 2012 · Contact Us: National Institute for Occupational Safety and Health (NIOSH) Centers for Disease Control and Prevention; 800-CDC-INFO (800-232-4636) TTY: (888 ...
  4. hydrogen cyanide | chemical compound |...

    www.britannica.com/science/hydrogen-cyanideCached
    Hydrogen cyanide, also called formonitrile (HCN), a highly volatile, colourless, and extremely poisonous liquid (boiling point 26° C [79° F], freezing point -14 ...
  5. Cyanide poisoning - Wikipedia, the free...

    en.wikipedia.org/wiki/Cyanide_poisoningCached
    Cyanide poisoning occurs when a living organism is exposed to a compound that produces cyanide ions (CN −) when dissolved in water. Common poisonous cyanide ... 

    Hydrogen cyanide

    From Wikipedia, the free encyclopedia
    Hydrogen cyanide
    Hydrogen-cyanide-2D.svg
    Ball and stick model of hydrogen cyanide
    Spacefill model of hydrogen cyanide
    Names
    IUPAC name
    • Formonitrile[1] (substitutive)
    • Hydridonitridocarbon[2] (additive)
    Other names
    • Formic anammonide
    • Hydrocyanic acid
    • Prussic acid
    • Methanenitrile
    Identifiers
    74-90-8 Yes
    3DMet B00275
    ChEBI CHEBI:18407 
    ChemSpider 748 
    EC number 200-821-6
    Jmol-3D images Image
    KEGG C01326 
    MeSH Hydrogen+Cyanide
    PubChem 768
    RTECS number MW6825000
    UNII 2WTB3V159F Yes
    UN number 1051
    Properties
    CHN
    Molar mass 27.03 g·mol−1
    Appearance Very pale, blue, transparent liquid or colorless gas
    Odor Oil of bitter almond
    Density 0.687 g mL−1
    Melting point −14 to −12 °C; 7 to 10 °F; 259 to 261 K
    Boiling point 25.6 to 26.6 °C; 78.0 to 79.8 °F; 298.7 to 299.7 K
    Miscible
    Solubility in ethanol Miscible
    Vapor pressure 630 mmHg (20°C)[3]
    75 μmol Pa−1 kg−1
    Acidity (pKa) 9.21[4]
    Basicity (pKb) 4.79
    1.2675 [5]
    Viscosity 201 μPa s
    Structure
    Linear
    2.98 D
    Thermochemistry
    71.00 kJ K−1 mol−1 (at 27 °C)[6]
    113.01 J K−1 mol−1
    109.9 kJ mol−1
    -426.5 kJ mol−1
    Hazards
    EU classification Extremely Flammable F+ Very Toxic T+ Dangerous for the Environment (Nature) N
    R-phrases R12, R26/27/28, R50/53
    S-phrases (S1/2), S16, S36/37, S38, S45, S53, S59, S61
    NFPA 704
    Flammability code 4: Will rapidly or completely vaporize at normal atmospheric pressure and temperature, or is readily dispersed in air and will burn readily. Flash point below 23 °C (73 °F). E.g., propane Health code 4: Very short exposure could cause death or major residual injury. E.g., VX gas Reactivity code 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g., calcium Special hazards (white): no codeNFPA 704 four-colored diamond
    4
    4
    1
    Flash point −17.8 °C (0.0 °F; 255.3 K)
    538 °C (1,000 °F; 811 K)
    Explosive limits 5.6% - 40.0%[3]
    Lethal dose or concentration (LD, LC):
    501 ppm (rat, 5 min)
    323 ppm (mouse, 5 min)
    275 ppm (rat, 15 min)
    170 ppm (rat, 30 min)
    160 ppm (rat, 30 min)
    323 ppm (rat, 5 min)[7]
    200 ppm (mammal, 5 min)
    36 ppm (mammal, 2 hr)
    107 ppm (human, 10 min)
    759 ppm (rabbit, 1 min)
    759 ppm (cat, 1 min)
    357 ppm (human, 2 min)
    179 ppm (human, 1 hr)[7]
    US health exposure limits (NIOSH):
    TWA 10 ppm (11 mg/m3) [skin][3]
    ST 4.7 ppm (5 mg/m3) [skin][3]
    50 ppm[3]
    Related compounds
    Related alkanenitriles
    Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
      verify (what isYes/?)
    Infobox references


    Hydrogen cyanide (HCN), sometimes called prussic acid, is an organic compound[8] with the chemical formula HCN. It is a colorless, extremely poisonous liquid that boils slightly above room temperature, at 25.6 °C (78.1 °F).[9] HCN is produced on an industrial scale and is a highly valuable precursor to many chemical compounds ranging from polymers to pharmaceuticals.

    Contents

    Structure and general properties

    Hydrogen cyanide is a linear molecule, with a triple bond between carbon and nitrogen. A minor tautomer of HCN is HNC, hydrogen isocyanide.
    Hydrogen cyanide is weakly acidic with a pKa of 9.2. It partially ionizes in water solution to give the cyanide anion, CN. A solution of hydrogen cyanide in water, represented as HCN, is called hydrocyanic acid. The salts of the cyanide anion are known as cyanides.
    HCN has a faint bitter almond-like odor that some people are unable to detect owing to a genetic trait.[10] The volatile compound has been used as inhalation rodenticide and human poison, as well as for killing whales.[11] Cyanide ions interfere with iron-containing respiratory enzymes.

    History of discovery


    The red colored ferricyanide ion, one component of Prussian blue
    Hydrogen cyanide was first isolated from a blue pigment (Prussian blue) which had been known since 1704 but whose structure was unknown. It is now known to be a coordination polymer with a complex structure and an empirical formula of hydrated ferric ferrocyanide. In 1752, the French chemist Pierre Macquer made the important step of showing that Prussian blue could be converted to iron oxide plus a volatile component and that these could be used to reconstitute it.[12] The new component was what we now know as hydrogen cyanide. Following Macquer's lead, it was first prepared from Prussian blue by the Swedish chemist Carl Wilhelm Scheele in 1782,[13] and was eventually given the German name Blausäure (lit. "Blue acid") because of its acidic nature in water and its derivation from Prussian blue. In English it became known popularly as Prussic acid.
    In 1787 the French chemist Claude Louis Berthollet showed that Prussic acid did not contain oxygen,[14] an important contribution to acid theory, which had hitherto postulated that acids must contain oxygen[15] (hence the name of oxygen itself, which is derived from Greek elements that mean "acid-former" and are likewise calqued into German as Sauerstoff). In 1811 Joseph Louis Gay-Lussac prepared pure, liquified hydrogen cyanide.[16] In 1815 Gay-Lussac deduced Prussic acid's chemical formula.[17] The radical cyanide in hydrogen cyanide was given its name from cyan, not only an English word for a shade of blue but the Greek word for blue (Ancient Greek: κυανοῦς), again owing to its derivation from Prussian blue.

    Production and synthesis

    Hydrogen cyanide forms in at least limited amounts from many combinations of hydrogen, carbon, and ammonia. Hydrogen cyanide is currently produced in great quantities by several processes, as well as being a recovered waste product from the manufacture of acrylonitrile.[8] In 2006 between 500 million and 1 billion pounds were produced in the US.[18]
    The most important process is the Andrussow oxidation invented by Leonid Andrussow at IG Farben in which methane and ammonia react in the presence of oxygen at about 1200 °C over a platinum catalyst:[19]
    2 CH4 + 2 NH3 + 3 O2 → 2 HCN + 6 H2O
    The energy needed for the reaction is provided by the partial oxidation of methane and ammonia.
    Of lesser importance is the Degussa process (BMA process) in which no oxygen is added and the energy must be transferred indirectly through the reactor wall:[20]
    CH4 + NH3 → HCN + 3H2
    This reaction is akin to steam reforming, the reaction of methane and water to give carbon monoxide and hydrogen.
    In the Shawinigan Process, hydrocarbons, e.g. propane, are reacted with ammonia. In the laboratory, small amounts of HCN are produced by the addition of acids to cyanide salts of alkali metals:
    H+ + NaCN → HCN + Na+
    This reaction is sometimes the basis of accidental poisonings because the acid converts a nonvolatile cyanide salt into the gaseous HCN.

    Historical methods of production

    The large demand for cyanides for mining operations in the 1890s was met by George Thomas Beilby, who patented a method to produce hydrogen cyanide by passing ammonia over glowing coal in 1892. This method was used until Hamilton Castner in 1894 developed a synthesis starting from coal, ammonia, and sodium yielding sodium cyanide, which reacts with acid to form gaseous HCN.

    Applications

    HCN is the precursor to sodium cyanide and potassium cyanide, which are used mainly in gold and silver mining and for the electroplating of those metals. Via the intermediacy of cyanohydrins, a variety of useful organic compounds are prepared from HCN including the monomer methyl methacrylate, from acetone, the amino acid methionine, via the Strecker synthesis, and the chelating agents EDTA and NTA. Via the hydrocyanation process, HCN is added to butadiene to give adiponitrile, a precursor to Nylon 66.[8]

    Occurrence

    HCN is obtainable from fruits that have a pit, such as cherries, apricots, apples, and bitter almonds, from which almond oil and flavoring are made. Many of these pits contain small amounts of cyanohydrins such as mandelonitrile and amygdalin, which slowly release hydrogen cyanide.[21][22] One hundred grams of crushed apple seeds can yield about 70 mg of HCN.[23] Some millipedes release hydrogen cyanide as a defense mechanism,[24] as do certain insects, such as some burnet moths. Hydrogen cyanide is contained in the exhaust of vehicles, in tobacco and wood smoke, and in smoke from burning nitrogen-containing plastics. So-called "bitter" roots of the cassava plant may contain up to 1 gram of HCN per kilogram.[25][26]

    HCN on the young Earth

    It has been postulated that carbon from a cascade of asteroids (known as the Late Heavy Bombardment), resulting from interaction of Jupiter and Saturn, blasted the surface of young Earth and reacted with nitrogen in Earth’s atmosphere to form HCN.[27]

    HCN in mammals

    Some authors have shown that neurons can produce hydrogen cyanide upon activation of their opioid receptors by endogenous or exogenous opioids. They have also shown that neuronal production of HCN activates NMDA receptors and plays a role in signal transduction between neuronal cells (neurotransmission). Moreover, increased endogenous neuronal HCN production under opioids was seemingly needed for adequate opioid analgesia, as analgesic action of opioids was attenuated by HCN scavengers. They considered endogenous HCN to be a neuromodulator.[28]
    It has also been shown that, while stimulating muscarinic cholinergic receptors in cultured pheochromocytoma cells increases HCN production, in a living organism (in vivo) muscarinic cholinergic stimulation actually decreases HCN production.[29]
    Leukocytes generate HCN during phagocytosis, and can kill bacteria, fungi, and other pathogens by generating several different toxic chemicals, one of which is hydrogen cyanide.[28]
    The vasodilatation, caused by sodium nitroprusside, has been shown to be mediated not only by NO generation, but also by endogenous cyanide generation, which adds not only toxicity, but also some additional antihypertensive efficacy compared to nitroglycerine and other non-cyanogenic nitrates which do not cause blood cyanide levels to rise.[30]

    HCN and the origin of life

    Hydrogen cyanide has been discussed as a precursor to amino acids and nucleic acids, and is proposed to have played a part in the origin of life.[31] Although the relationship of these chemical reactions to the origin of life theory remains speculative, studies in this area have led to discoveries of new pathways to organic compounds derived from the condensation of HCN.[32]

    HCN in space

    See also: Astrochemistry
    HCN has been detected in the interstellar medium.[33] Since then, extensive studies have probed formation and destruction pathways of HCN in various environments and examined its use as a tracer for a variety of astronomical species and processes. HCN can be observed from ground-based telescopes through a number of atmospheric windows.[34] The J=1→0, J=3→2, J= 4→3, and J=10→9 pure rotational transitions have all been observed.[33][35][36]
    HCN is formed in interstellar clouds through one of two major pathways:[37] via a neutral-neutral reaction (CH2 + N → HCN + H) and via dissociative recombination (HCNH+ + e → HCN + H). The dissociative recombination pathway is dominant by 30%; however, the HCNH+ must be in its linear form. Dissociative recombination with its structural isomer, H2NC+, exclusively produces hydrogen isocyanide (HNC).
    HCN is destroyed in interstellar clouds through a number of mechanisms depending on the location in the cloud.[37] In photon-dominated regions (PDRs), photodissociation dominates, producing CN (HCN + ν → CN + H). At further depths, photodissociation by cosmic rays dominate, producing CN (HCN + cr → CN + H). In the dark core, two competing mechanisms destroy it, forming HCN+ and HCNH+ (HCN + H+ → HCN+ + H; HCN + HCO+ → HCNH+ + CO). The reaction with HCO+ dominates by a factor of ~3.5. HCN has been used to analyze a variety of species and processes in the interstellar medium. It has been suggested as a tracer for dense molecular gas[38][39] and as a tracer of stellar inflow in high-mass star-forming regions.[40] Further, the HNC/HCN ratio has been shown to be an excellent method for distinguishing between PDRs and X-ray-dominated regions (XDRs).[41]
    On 11 August 2014, astronomers released studies, using the Atacama Large Millimeter/Submillimeter Array (ALMA) for the first time, that detailed the distribution of HCN, HNC, H2CO, and dust inside the comae of comets C/2012 F6 (Lemmon) and C/2012 S1 (ISON).[42][43]

    As a poison and chemical weapon

    Main article: Cyanide poisoning
    A hydrogen cyanide concentration of 300 mg/m3 in air will kill a human within 10–60 minutes.[44] A hydrogen cyanide concentration of 3500 ppm (about 3200 mg/m3) will kill a human in about 1 minute.[44] The toxicity is caused by the cyanide ion, which halts cellular respiration by acting as a non-competitive inhibitor for an enzyme in mitochondria called cytochrome c oxidase. Specifically CN binds to Fe in the heme subunit in cytochromes, interrupting electron transfer.
    Hydrogen cyanide has been absorbed into a carrier for use as a pesticide. Under IG Farben's brand name Zyklon B (German >Cyclone B, with the B standing for Blausäure - "Prussic Acid"),[45] it was used in the German extermination camps mass killings during World War II. The same product is currently made in the Czech Republic under the trademark "Uragan D2". Hydrogen cyanide was also the agent employed in judicial execution in some U.S. states, where it was produced during the execution by the action of sulfuric acid on an egg-sized mass of potassium cyanide.[not specific enough to verify]
    Hydrogen cyanide is commonly listed amongst chemical warfare agents known as blood agents.[46] As a substance listed under Schedule 3 of the Chemical Weapons Convention as a potential weapon which has large-scale industrial uses, manufacturing plants in signatory countries which produce more than 30 tonnes per year must be declared to, and can be inspected by, the Organisation for the Prohibition of Chemical Weapons. During the First World War, the United States and Italy used hydrogen cyanide against the Central Powers in 1918. France had used it in combat already in 1916, but this proved to be ineffective due to physical conditions.[47]
    Under the name prussic acid, HCN has been used as a killing agent in whaling harpoons.[48] From the mid 18th century it was used in a number of poisoning murders and suicides.[49] Cyanide has also been used in major occurrences of suicide in the 20th century, including the deaths of over 900 people at Jonestown and the mass suicides in 1945 Nazi Germany.
    Hydrogen cyanide gas in air is explosive at concentrations over 5.6%.[50] This is far above its toxicity level.

    References


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  • External links


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  • "NIOSH Pocket Guide to Chemical Hazards #0333". National Institute for Occupational Safety and Health (NIOSH).

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  • Patnaik, P. (2002). Handbook of Inorganic Chemicals. McGraw-Hill. ISBN 0-07-049439-8.

  • NIST Chemistry WebBook

  • "Hydrogen cyanide". Immediately Dangerous to Life and Health. National Institute for Occupational Safety and Health (NIOSH).

  • Gail, E.; Gos, S.; Kulzer, R.; Lorösch, J.; Rubo, A.; Sauer, M. (2005), "Cyano Compounds, Inorganic", Ullmann's Encyclopedia of Industrial Chemistry, Weinheim: Wiley-VCH, doi:10.1002/14356007.a08_159.pub2

  • http://www.wolframalpha.com/input/?i=boiling+point+of+Hydrogen+cyanide

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  • Pierre-Joseph Macquer (presented: 1752 ; published: 1756) "Éxamen chymique de bleu de Prusse" (Chemical examination of Prussian blue), Mémoires de l'Académie royale des Sciences , pages 60-77.

  • See:
    • Carl W. Scheele (1782) "Försök, beträffande det färgande ämnet uti Berlinerblå" (Experiment concerning the coloring substance in Berlin blue), Kungliga Svenska Vetenskapsakademiens handlingar (Royal Swedish Academy of Science's Proceedings), 3: 264-275 (in Swedish).
    • Reprinted in Latin as: "De materia tingente caerulei berolinensis" in: Carl Wilhelm Scheele with Ernst Benjamin Gottlieb Hebenstreit (ed.) and Gottfried Heinrich Schäfer (trans.), Opuscula Chemica et Physica (Leipzig ("Lipsiae"), (Germany): Johann Godfried Müller, 1789), vol. 2, pages 148-174.

  • See:
    • Berthollet (presented: 1787 ; published: 1789)
    "Mémoire sur l'acide prussique" (Memoir on prussic acid), Mémoires de l'Académie Royale des Sciences, pages 148-161.

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  • Cordiner, M.A. et al. (11 August 2014). "Mapping the Release of Volatiles in the Inner Comae of Comets C/2012 F6 (Lemmon) and C/2012 S1 (ISON) Using the Atacama Large Millimeter/Submillimeter Array". The Astrophysical Journal 792 (1). doi:10.1088/2041-8205/792/1/L2. Retrieved 12 August 2014.

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